无机材料学报

• 研究论文 • 上一篇    下一篇

钛掺杂有序多孔氧化锆的研究

陈航榕1,2; 施剑林1; 张文华1; 阮美玲1; 严东生1   

  1. 1. 中国科学院上海硅酸盐研究所高性能陶瓷与超微结构国家重点实验室, 上海 200050; 2. 福州大学材料学院, 福州 350002
  • 收稿日期:2000-06-02 修回日期:2000-06-30 出版日期:2001-05-20 网络出版日期:2001-05-20

Titanium-doped Ordered Porous Zirconium Oxide

CHEN Hang-Rong1,2; SHI Jian-Lin1; ZHANG Wen-Hua1; RUAN Mei-Ling1; YAN Dong-Sheng 1   

  1. 1. State Key Lab of High Performance Ceramics and Superfine Microstructure; Shanghai Institute of Ce- ramics; Chinese Academy of Sciences; Shanghai 200050; China; 2. School of Materials, Fuzhou University, Fuzhou 350002, China
  • Received:2000-06-02 Revised:2000-06-30 Published:2001-05-20 Online:2001-05-20

摘要: 利用表面活性剂辅助途径,水热条件下合成了含钛的有序多孔氧化锆.通过XRD、N吸附、HRTEM、UV-VIS吸收光谱、Raman光谱等手段对不同按量的钛掺杂多孔氧化锆进行研究.结果表明,<15mol%的钛掺杂有利于提高材料的比表面积;钛掺量<30mol%时,钛能很好进入氧化锆骨架中,但随着掺量增加,孔道有序性降低.掺量>30mol%,多余的钛将以纳米晶TiO形式析出.

关键词: 钛掺杂, 多孔氧化锆, 掺量

Abstract: Zirconium oxide containing titanium with ordered pore-arrangement was synthesized by the surfactant-
assisted route, under the hydrothermal condition. X-ray powder diffraction, nitrogen adsorption, TEM, UV-Vis spectroscopy and Raman spectroscopy
methods were adopted for the study on the synthesized materials. The results obtained show that it is helpful to increase the BET surface areas when the
amount of titanium is less than 15mol%, and that less than 30mol% of doping of titanium can be successfully incorporated into the
framework of zirconium oxide. Nevertheless, the ordering of the pore structure will decrease with the amount of doping and the noncrystal
titania will appear on the surface of the pore structure, once the amount of doping is more than 30mol%.

Key words: titanium incorporation, porous zirconium oxide, amount of doping

中图分类号: