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无机材料学报

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聚乙烯亚胺在SiC粉体上的定量吸附研究

孙静; 孙伟燕; 高濂; 郭景坤   

  1. 中国科学院上海硅酸盐研究所高性能陶瓷与超微结构国家重点实验室, 上海 200050
  • 收稿日期:1999-04-27 修回日期:1999-08-24 出版日期:2000-04-20 网络出版日期:2000-04-20

Adsorption Behaviour of PEI on Silicon Carbide Powder

SUN Jing; SUN Wei-Yan; GAO Lian; GUO Jing--Kun   

  1. State Key Lab of High Performance Ceramics & Superfine Microstructure; Shanghai Institute of Ceramics; Chinese Academy of Sciences; Shanghai 200050; China
  • Received:1999-04-27 Revised:1999-08-24 Published:2000-04-20 Online:2000-04-20

PDF (PC)

1217

被引次数

42

摘要： 利用紫外一可见光谱研究了分散剂聚乙烯亚胺在粉体ＳｉＣ上的定量吸附情况．加入酸性ＰＥＩ后粉体ＳｉＣ表面的电性发生改变，等电点由ｐＨ＝２．０移至ｐＨ＝１０．５．分散剂在粉体上的吸附满足Ｌａｎｇｍｕｉｒ单层吸附方程．对分散剂ＰＥＩ－Ｈ＋（ｐＨ＝３．５７）来说，单层吸附值为０．０１７２ｍｇ／ｍＬ．对分散剂ＰＥＩ－Ｈ＋（ｐＨ＝６６１）来说，单层吸附值为０．０２０８ｍｇ／ｍＬ．利用富利叶红外光谱证实了这种吸附作用．

关键词: 聚乙烯亚胺, 定量吸附, 紫外光谱, SiC粉体

Abstract: Adsorption behaviour of PEI on silicon carbide powder was measured by using UV spectrum. The surface charge of SiC powder was changed greatly after
the addition of PEI, its IEP changed from pH=2.0 to pH=10.5. Adsorption isotherms of dispersant on the silicon carbide surface were investigated.
Their adsorption behaviour belongs to Langmuir monolayer adsorption type. The maximum amount of PEI--H+(pH=3.57) adsorbed on the SiC surface is
0.0172mg/mL and that of PEI--H+(pH=6.61) is 0.0208mg/mL. IR spectra were obtained to verify this adsorption effect.

Key words: polyethylene imine (PEI), quantitative adsorption, UV spectrum silicon carbid

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