掺杂PbS纳米粒子的有机改性硅酸盐玻璃

无机材料学报

掺杂PbS纳米粒子的有机改性硅酸盐玻璃

董文庭; 朱从善

中国科学院上海光学精密机械研究所, 上海 201800

收稿日期:1998-09-10 修回日期:1999-10-20 出版日期:1999-08-20 网络出版日期:1999-08-20

Preparation and Characterization of DBS Modificated PbS Nanoparticles Doped in ORMOSIL

DONG Wen-Ting ZHU Cong-Shan

Shanghai Institute of Optics and Fine Michanics; Chinese Academy of Sciences Shanghai 201800 China

Received:1998-09-10 Revised:1999-10-20 Published:1999-08-20 Online:1999-08-20

摘要/Abstract

摘要： 本文报道了用溶胶凝胶法将表面修饰的ＰｂＳ纳米粒子均匀固化于有机改性硅酸盐玻璃中的制备方法，制得的ＰｂＳ在改性硅酸盐玻璃中的掺杂浓度为０.５ｗｔ％，ＨＲＴＥＭ显示ＰｂＳ纳米粒子的尺寸为３～４ｎｍ在吸收光谱中，可以观察到明显的量子尺寸效应，吸收边蓝移

关键词: 有机改性硅酸盐（ORMOSIL）, 硫化铅纳米粒子, 量子尺寸效应

Abstract: Samples of DBS modified PbS nanoparticles doped in ORMOSIL were prepared by Sol Gel method and characterized The HRTEM demonstrated that the sizes of PbS nanoparticles are 3～4nm and that the particles separately and homogeneously disperse in the ORMOSIL The blue shift of the absorption edge shows an obvious quantum size effect.

Key words: ORMOSIL, PbS nanoparticle, quantum size effect

中图分类号:

TQ171

董文庭,朱从善. 掺杂PbS纳米粒子的有机改性硅酸盐玻璃[J]. 无机材料学报.

DONG Wen-Ting ZHU Cong-Shan. Preparation and Characterization of DBS Modificated PbS Nanoparticles Doped in ORMOSIL[J]. Journal of Inorganic Materials.

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