低电位泡沫石墨改性阳极及其在海底微生物燃料电池中的应用

doi:10.3724/SP.J.1077.2013.12245

无机材料学报 ›› 2013, Vol. 28 ›› Issue (3): 278-282.DOI: 10.3724/SP.J.1077.2013.12245 CSTR: 32189.14.SP.J.1077.2013.12245

低电位泡沫石墨改性阳极及其在海底微生物燃料电池中的应用

卢志凯, 付玉彬, 徐谦, 刘媛媛, 张业龙

(中国海洋大学材料科学与工程研究院, 青岛 266100)

收稿日期:2012-04-19 修回日期:2012-07-05 出版日期:2013-03-20 网络出版日期:2013-02-20
作者简介:卢志凯(1985–), 男, 硕士研究生. E-mail: zhikailu@163.com
基金资助:
国家海洋局可再生能源专项基金(GHME2011GD04); 山东省重点自然科学基金(ZR2011BZ008)

Application of Modified Foam Graphite Anode with Low Potential in Marine Benthic Microbial Fuel Cell

LU Zhi-Kai, FU Yu-Bin, XU Qian, LIU Yuan-Yuan, ZHANG Ye-Long

(Institute of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China)

Received:2012-04-19 Revised:2012-07-05 Published:2013-03-20 Online:2013-02-20
About author:LU Zhi-Kai. E-mail: zhikailu@163.com
Supported by:
Project of Marine Renewable Energy from State Ocean Bureau (GHME2011GD04); Key Project of Natural Science from Shandong Province (ZR2011BZ008)

摘要/Abstract

摘要： 泡沫石墨是一种新型阳极材料, 对其进行改性是提高海底微生物燃料电池性能的重要途径之一。本文研究了混酸改性泡沫石墨阳极及其电化学性能。研究表明:改性后泡沫石墨表面生成羟基、羧基等含氧官能团; 改性阳极接触角降低了24.5°, 润湿性提高, 有利于微生物附着; 交换电流密度达到6760.8 mA/m², 动力学活性提高了53.7倍。研究还发现改性后阳极电位降低了100 mV, 电池开路电位达到865 mV (未改性750 mV), 最大输出功率密度为358.1 mW/m², 提高了2.4倍。三个月放电测试显示, 改性阳极和电池具有相对稳定的性能。同时, 本文初步分析了改性后阳极动力学活性增加和电位降低的原因。该研究结果为构建高输出电压和功率的海底微生物燃料电池提供了依据。

关键词: 海底微生物燃料电池, 改性泡沫石墨, 低电位阳极, 高输出功率

Abstract: Foam graphite is a novel anode material and its modification is one important way to increase the performance of marine benthic microbial fuel cell. The electrochemical performance of mixed-acid modified foam graphite anode was investigated. The results showed that the hydroxyl and carboxyl groups were introduced on foam graphite surface after modification. The contact angle of modified anode decreased 24.5°, resulting in higher wettability and better attachment for bacteria. Its exchange current density reached 6760.8 mA/m² and the kinetic activity was improved 53.7-fold higher than the original one. Additionally, the present study also found that the anode potential of modified decreased 100 mV, and its open circuit potential reached 865 mV (plain anode 750 mV). The power density of modified cell reached 358.1 mW/m², 2.4-fold higher than unmodified foam. Three months discharge showed that the modified anode and its cell have relatively stable performance. Meanwhile, the paper primarily analyzed the reasons why the anode potential was lower and kinetic activity was higher after modification. The results gave some enlightenments to constructing a novel marine benthic microbial fuel cell with higher output voltage and power.

Key words: marine benthic microbial fuel cell, modified foam graphite, low anode potential, high output power

中图分类号:

TM911

卢志凯, 付玉彬, 徐谦, 刘媛媛, 张业龙. 低电位泡沫石墨改性阳极及其在海底微生物燃料电池中的应用[J]. 无机材料学报, 2013, 28(3): 278-282.

LU Zhi-Kai, FU Yu-Bin, XU Qian, LIU Yuan-Yuan, ZHANG Ye-Long. Application of Modified Foam Graphite Anode with Low Potential in Marine Benthic Microbial Fuel Cell[J]. Journal of Inorganic Materials, 2013, 28(3): 278-282.

参考文献

[1] Ashley E F, Kelly P N. Microbial fuel cells, a current review. Energies, 2010, 3(10): 899–919.

[2] Wei J C, Liang P, Huang X. Recent progress in electrodes for microbial fuel cells. Bioresource Technology, 2011, 102(20): 9335–9344.

[3] Logan B E, Hanelers B, Rozendal R. Microbial fuel cells: methodology and technology. Environmental Science and Technology, 2006, 40(17): 5181–5190.

[4] Chaudhuri S K, Lovley D R. Electricity generation by direct oxidation of glucose in mediatorless microbial fuel cells. Nature Biotechnology, 2003, 21(10): 1229–1232.

[5] Zhao Z Y, Li P J, Meng Q H. Synthesis of 2,2'-dichlorohydrazo- benzene using porous Ni-Fe electrode. Chemical Industry and Engineering Progress, 2010, 29(9): 1640–1646.

[6] Hu J S. Li Q Y, Huang S W, et al. Synthesis and characteristics of porous Sn thin film on foam copper as anode material. The Chinese Journal of Nonferrous Metals, 2009, 19(11): 2006–2010.

[7] Wen N Y. Electrochemical applications of carbon foam electrode. America: a master thesis of Michigan Technological university. 2003.

[8] Mastragostino M, Valcher, S. Polymeric salt as bromine complexing agent in a Zn-Br model. Battery. 1983, 28(4): 501–505.

[9] Gyenge E, Jung J, Mahato B. Electroplated reticulated vitreous carbon current collectors for lead acid batteries: opportunities and challenges. Journal of Power Sources, 2003, 113(2): 388–395.

[10] Tang X H, Guo K, Li H R, et al. Electrochemical treatment of graphite to enhance electron transfer from bacteria to electrodes. Bioresource Technology. 2011, 102(3): 3558–3560.

[11] Qiao Y, Bao S J, Li C M, et al. Nanostructured polyaniline/ titanium dioxide composite anode for microbial fuel cells. ACS Nano. 2008, 2(1): 113–119.

[12] Wang X, Cheng S A, Feng Y J, et al. Use of carbon mesh anodes and the effect of different pretreatment methods on power production in microbial fuel cells. Environmental Science and Technology, 2009, 43(17): 6870–6874.

[13] Lowy D A, Tender L M, Zeikus J G, et al. Harvesting energy from the marine sediment-water interface Ⅱ: Kinetic activity of anode materials. Biosensors and Bioelectronics, 2006, 21(11): 2058–2063.

[14] 李建海. 海底沉积物微生物燃料电池阳极表面改性及电极构型研究. 青岛: 中国海洋大学硕士论文, 2010.

[15] Scot K, Cotlarcius I, Head I, et al. Fuel cell power generation from marine sediments: Investigation of cathode materials. Chemical Technology and Biotechnology, 2008, 83: 1244–1254.

[16] 傅献彩, 沈文霞, 姚天扬, 等. 物理化学, 5版. 北京: 高等教育出版社, 2006: 119–121.

[17] 付玉彬, 徐谦, 卢志凯, 等. 一种高输出电压和功率的海底沉积层微生物燃料电池的构建方法. 中国, H01M4/88, CN 201110443474.x.

Song T S, Cai H Y, Yan Z S, et al. Various voltage productions by microbial fuel cells with sedimentary inocula taken from different sites in one freshwater lake. Bioresource Technology. 2012, 108(3): 68–75.

低电位泡沫石墨改性阳极及其在海底微生物燃料电池中的应用

Application of Modified Foam Graphite Anode with Low Potential in Marine Benthic Microbial Fuel Cell

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	曹珍珠, 任伟, 刘进荣, 李国荣, 高艳芳, 房明浩, 何伟艳. Sb掺杂Li₇La₃Zr₂O₁₂陶瓷的显微结构及离子导电性能研究[J]. 无机材料学报, 2014, 29(2): 220-224.
[2]	郑玥雷, 陈人杰,吴锋,李丽. 锂离子电池玻璃态电解质导电机理的研究进展[J]. 无机材料学报, 2013, 28(11): 1172-1180.
[3]	彭鹏, 刘宇, 温兆银. 锂离子电池Si/C/石墨复合负极材料的电化学性能[J]. 无机材料学报, 2013, 28(11): 1195-1199.
[4]	赵文文, 张华, 李梅. 恒压电沉积Pt-Fe合金催化剂及在PEMFC阴极的应用[J]. 无机材料学报, 2013, 28(11): 1217-1222.
[5]	孙琳, 卢军, 殷洁炜, 尹屹梅, 马紫峰. 新型SOFC阳极材料La_0.75Sr_0.25Mn_0.5Cr_0.5-xCu_xO_3-δ的合成与表征[J]. 无机材料学报, 2013, 28(9): 925-930.
[6]	张治安, 周耿, 彭彬, 卢海, 贾明, 赖延清, 李劼. 锂空气电池用碳纳米管/钴锰氧化物复合电极材料的制备及电化学性能[J]. 无机材料学报, 2013, 28(9): 949-955.
[7]	王欢, 张华, 靳宏建, 赵文文. 燃料对甘氨酸-硝酸盐法合成Gd_0.8Sr_0.2CoO_3-δ阴极材料的影响[J]. 无机材料学报, 2013, 28(8): 818-824.
[8]	熊明文, 尹屹梅, 原鲜霞, 马紫峰. 中温固体氧化物燃料电池阴极材料SrCo_1-xGa_xO_3-δ的制备及性能研究[J]. 无机材料学报, 2013, 28(7): 713-719.
[9]	赵东江, 马松艳, 尹鸽平. CoSeO₃化合物的制备及对阴极氧还原的催化性能[J]. 无机材料学报, 2013, 28(06): 644-648.
[10]	王松林, 凤仪, 王东生, 孟广耀. 新型复合支撑体共烧制备致密La_0.7Ca_0.3Cr_0.97O_3−δ连接体薄膜[J]. 无机材料学报, 2012, 27(9): 911-916.
[11]	李艳红, 邱新平, 刘源. 真空蒸镀法制备Sb膜电极及其性能[J]. 无机材料学报, 2012, 27(7): 746-750.
[12]	靳宏建, 王欢, 张华, 金江. 甘氨酸-硝酸盐法合成GdBaCo₂O_5+δ阴极材料及其性能[J]. 无机材料学报, 2012, 27(7): 751-756.
[13]	李淑君, 葛林, 郑益锋, 周明, 陈涵, 郭露村. EDTA-柠檬酸络合法制备(Ce_0.8Y_0.2-xNd_xO_1.9)_0.99(ZnO)_0.01电解质材料及其性能研究[J]. 无机材料学报, 2012, 27(3): 265-270.
[14]	张新龙, 胡国荣, 彭忠东. 锂离子电池负极材料钼掺杂钛酸锂的制备及电化学表征[J]. 无机材料学报, 2011, 26(4): 443-448.
[15]	努丽燕娜, 杨军, 郑育培, 王久林. 介孔硅酸锰镁可充镁电池正极材料的制备及其电化学性能研究[J]. 无机材料学报, 2011, 26(2): 129-133.