无机材料学报

• 研究论文 •    

激光照明用GdYAG:Ce/LuAG:Ce复合荧光薄膜性能优化

李跃辉1, 郭杨涵1, 刘丙国1, 徐坚1,2, 杜保立1, JENSEN Ole3   

  1. 1.河南理工大学 物理与电子信息学院, 河南 454000;
    2.河南聚盏光电有限公司, 河南 454003;
    3.丹麦技术大学 院系 光电工程学院, 罗斯基勒 4000
  • 收稿日期:2026-03-22 修回日期:2026-04-24
  • 作者简介:李跃辉(2001–),男,硕士研究生.E-mail:212412020032@home.hpu.edu.cn
  • 基金资助:
    国家自然科学基金(51772076,51802083)

Optimization of GdYAG:Ce/LuAG:Ce Composite Phosphor Films for Laser Lighting

LI Yuehui1, GUO Yanghan1, LIU Bingguo1, XU Jian1,2, DU Baoli1, JENSEN Ole3   

  1. 1. School of Physics and Electronic Information, Henan Polytechnic University, Henan 454000, China;
    2. Henan Juzhan Electro. Ltd, Henan 454003, China;
    3. Department of Electrical and Photonics Engineering, Technical University of Denmark, Roskilde 4000, Denmark
  • Received:2026-03-22 Revised:2026-04-24
  • About author:LI Yuehui (2001–), male, Master candidate. E-mail:212412020032@hpu.edu.cn
  • Supported by:
    National Natural Science Foundation of China (51772076, 51802083)

摘要: 高功率激光照明对荧光转换材料的发光效能、显色性能和热稳定性均提出了较高要求,而单一荧光粉体系通常难以同时满足上述要求。本研究采用丝网印刷技术,在氧化铝基板上制备了GdYAG:Ce/LuAG:Ce复合荧光薄膜,系统研究了玻璃粉对荧光粉质量比(Glass-to-phosphor, GtP)及两种荧光粉配比对其微观结构和光学性能的影响。研究表明,随着GtP增加,荧光粉颗粒间连接方式由颈部连接逐渐转变为玻璃基质黏结,且未观察到玻璃基质对荧光粉晶粒的明显腐蚀;随着LuAG:Ce比例增加,样品发射峰由568 nm蓝移至520 nm,光通量持续升高。优化后的样品在3.2 W蓝光激光激发下,光通量达到462 lm,且未出现明显发光饱和,发光效能为198 lm/W,显色指数为67,相关色温保持在7300~12500 K范围内,光出射度均超过1100 lm/mm²。结合不同激光功率下的红外热成像结果可知,样品在较高功率激发下仍保持较好的发光稳定性,具有一定的抗热饱和能力。因此,通过调控GtP和两种荧光粉配比,可实现光效、色品质与热稳定性的协同优化,为复合荧光薄膜在高功率激光照明中的应用提供了参考。

关键词: 激光照明, 复合荧光薄膜, GdYAG:Ce, LuAG:Ce, 协同优化

Abstract: High-power laser lighting has set stringent requirements on phosphor conversion materials in terms of luminous efficacy, color rendering performance, and thermal stability, whereas a single phosphor usually cannot simultaneously satisfy these requirements. In this work, GdYAG:Ce/LuAG:Ce composite phosphor films were fabricated on alumina substrates by screen printing, and the effects of the ratio of glass-to-phosphor (GtP) and the ratio of the two phosphors on their microstructure and optical properties were systematically investigated. The results show that, with increasing GtP, the connection mode between phosphor particles gradually changed from necking to bonding by the glass matrix, and no obvious corrosion of phosphor grains caused by the glass matrix was observed. As the LuAG:Ce content increased, the emission peak of the samples blue-shifted from 568 nm to 520 nm, accompanied by a continuous increase in luminous flux. The optimized sample achieved a luminous flux of 462 lm under 3.2 W blue-laser excitation without significant luminescence saturation. It had a luminous efficacy of 198 lm/W, and a color rendering index of 67. The correlated color temperature remained in the range of 7300-12500 K, and the luminous exitance was higher than 1100 lm/mm2. Infrared thermal imaging results under different laser powers demonstrate that the sample maintains excellent luminescence stability even at high power excitation, exhibiting strong resistance to thermal saturation. These results demonstrate that synergistic optimization of luminous efficacy, color quality, and operational stability can be achieved by regulating the GtP and the composition of the phosphors, providing a useful reference for the performance optimization and application of composite phosphor films in high-power laser lighting.

Key words: laser lighting, composite phosphor films, GdYAG:Ce, LuAG:Ce, synergistic optimization

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