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2006 , Vol. 21 >Issue 6: 1307 - 1312

DOI: https://doi.org/10.3724/SP.J.1077.2006.01307

研究论文

微晶玻璃的制备与光谱特性

  • 张约品 ,
  • 夏海平 ,
  • 张新民 ,
  • 王金浩 ,
  • 姜淳
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  • (1. 宁波大学光电子功能材料研究所, 宁波 315211; 2. 上海交通大学电子信息学院, 上海 200030)

收稿日期: 2005-12-12

  修回日期: 2006-03-17

  网络出版日期: 2006-11-20

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Preparation and Spectroscopic Properties of Yb:YAG Glass-ceramics

  • ZHANG Yue-Pin ,
  • XIA Hai-Ping ,
  • ZHANG Xin-Min ,
  • WANG Jin-Hao ,
  • JIANG Chun
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  • (1. Laboratory of Photo-Electronic Material, Ningbo University, Ningbo 315211, China; 2. Department of Electronic Science and Technology, Shanghai Jiaotong University, Shanghai 200030, China)

Received date: 2005-12-12

  Revised date: 2006-03-17

  Online published: 2006-11-20

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摘要

高温熔制摩尔组分为32CaO-12Y2O3-24Al2O3-31SiO2-1Yb2O3的玻璃, 制得的玻璃于950、1050、1100℃三个不同温度进行热处理, 用XRD分析热处理后样品的相变, 用TEM观察1050℃热处理后的样品, 并研究了1050℃热处理前后样品的光谱特性. 研究结果表明: 玻璃在1050℃热处理后, 在玻璃中产生单一YAG相微晶颗粒; 热处理前后样品光谱特性的变化表明热处理后掺杂的Yb 3+离子择优进入到YAG晶格位, 制备得到了透明Yb:YAG微晶玻璃.

关键词： 镱:钇铝石榴石; 微晶玻璃; 制备; 光谱特性

本文引用格式

张约品 , 夏海平 , 张新民 , 王金浩 , 姜淳 . 微晶玻璃的制备与光谱特性[J]. 无机材料学报, 2006 , 21(6) : 1307 -1312 . DOI: 10.3724/SP.J.1077.2006.01307

Abstract

The Yb 3+ -doped 32CaO-12Y2O3-24Al2O3-31SiO2-1Yb2O3glasses were prepared by a melting method, then the glasses were annealed at 950C, 1050C and 1100C. The crystallographic structures of the glasses annealed at different temperatures were analyzed by XRD, the glass annealed at 1050℃ was observed by TEM. The spectroscopic properties of the glass before and after annealing were investigated. The results show that the glass annealed at 1050℃is YAG glass-ceramics with no impurity crystalline phase. The spectroscopic properties indicate that Yb3+ ions are preferentially entered into the YAG crystal phase. The transparent Yb:YAG glass-ceramics obtained are based on the controlled nucleation and crystallization of CaO-Y2O3-Al2O3-SiO2 system glasses containing Yb 3+ ions.

Key words： Yb:YAG; glass-ceramics; preparation; spectroscopic properties

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