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2006 , Vol. 21 >Issue 3: 576 - 582

DOI: https://doi.org/10.3724/SP.J.1077.2006.00576

研究论文

微波等离子体法合成洋葱状富勒烯的研究

  • 符冬菊 ,
  • 刘旭光 ,
  • 杜爱兵 ,
  • 韩培德 ,
  • 贾虎生 ,
  • 许并社
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  • 1. 太原理工大学材料科学与工程学院, 太原030024;
    2. 太原理工大学化学化工学院, 太原 030024

收稿日期: 2005-06-13

  修回日期: 2005-11-21

  网络出版日期: 2006-05-20

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Synthesis of Nano-structured Onion-like Fullerenes by MW Plasma

  • FU Dong-Ju ,
  • LIU Xu-Guang ,
  • DU Ai-Bing ,
  • HAN Pei-De ,
  • JIA Hu-Sheng ,
  • XU Bing-She
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  • 1. College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China;
    2. College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Received date: 2005-06-13

  Revised date: 2005-11-21

  Online published: 2006-05-20

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摘要

在微波等离子体条件下, 以乙炔炭黑/二茂铁为原料, 低温合成纳米洋葱状富勒烯(Nano-structured Onion-like Fullerenes: NSOFs). 采用HRTEM、Raman和XRD等分析方法对产物的形貌、尺寸、微观结构及其物相结构进行了表征. 结果表明, 以乙炔炭黑/二茂铁为原料可大量合成NSOFs, 其外观呈准球状或多面体状、实心、直径分布均匀, 最外碳层由闭合的、呈波浪状的石墨片构成.

关键词： 纳米洋葱状富勒烯; 微波等离子体; 炭黑

本文引用格式

符冬菊 , 刘旭光 , 杜爱兵 , 韩培德 , 贾虎生 , 许并社 . 微波等离子体法合成洋葱状富勒烯的研究[J]. 无机材料学报, 2006 , 21(3) : 576 -582 . DOI: 10.3724/SP.J.1077.2006.00576

Abstract

Nano-structured onion-like fullerenes (NSOFs) were synthesized from C2H2 carbon black/ferrocene by microwave plasma. High resolution transmission electron microscope (HRTEM), Raman and X-ray diffraction (XRD) techniques were used to characterize the morphologies and structures of the products. Results indicated that NSOFs could be prepared from C2H2 carbon black/ferrocene. The particles displayed a clear polyhedral or spherical morphology, with cores and waving out layers.

Key words： nano-structured onion-like fullerenes; microwave plasma; carbon black

参考文献

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