通过在紫罗精溶液中加入钛离子, 得到了一种新型互补型的电致变色溶液. 利用这种电致变色溶液设计成电致变色器件, 通过紫外-可见分光光度计表征, 这种溶液型电致变色器件透过率变化在600nm附近可由80%降低到20%; 通过电致变色器件和透射光强变化的关系, 测得其退色时间<2s, 并且具有自擦除效果.
A new coupling electrochromic solution was investigated by introducing titanium ion into viologen solution. The solution-based electrochromic device was assembled by using this coupling solution. The transmittance of this electrochromic device decreased from 80% to 20% in the wavelength of 600nm, which was characterized by UV-Vis spectra. The bleaching time of this electrochromic device was less than 2s and this electrochromic device had a character of self-erasing process.
1 Choi S Y, Mamak M, Coombs N. Nano Letters, 2004, 4 (7): 1231-1235.
2 Michaelis A, Berneth H. Advanced Materials, 2001, 13 (23): 1825-1828.
3 Bach U, Corr D. Advance Materials, 2002, 14(11): 845-848 .
4 Granqvist C G. Sol. Energy Mater. Sol. Cells, 2000, 60: 201-207.
5 Hashimoto S, Matsuoka H. Appl. Phys., 1991, 69: 933-936.
6 Wruck D. Thin Solid Films, 1989, 182: 79-83.
7 Zelaya-Angel O. J. Appl. Phys., 1980, 51: 6022-6027.
8 Ozer N. Ceramic. Transactions, 1991, 20: 265-273.
9 Hutchins M G. Proceedings of SPIE, 1990, 1272: 139-143.
10 Gr\ddot atzel M. Nature, 2001, 409: 575-576.
11 Alvaro M. Chem. Phys. Chem., 2004, 5: 1058-1062.
12 Michaelis L, Hill E S. J. Gen. Physiol., 1933, 16: 859-873.
13 Byker H J. Electrochimica Acta, 2001, 46: 2015-2022.
14 Byker H J. Zeeland, Mich. US Patent 5 336 448. 1994