高级检索
无机材料学报

无机材料学报 >

2010 , Vol. 25 >Issue 4: 379 - 385

DOI: https://doi.org/10.3724/SP.J.1077.2010.00379

研究论文

钇或钕掺杂TiO2纳米纤维的制备及光催化性能研究

  • 王进贤 ,
  • 郭月秋 ,
  • 董相廷 ,
  • 李志国 ,
  • 刘桂霞
展开

  • 长春理工大学 化学与环境工程学院， 长春 130022

收稿日期: 2009-08-10

  修回日期: 2009-11-17

  网络出版日期: 2010-04-27

收起

Preparation and Photocatalytic Activities of Y3+ or Nd3+doped TiO2 Nanofibres

  • WANG Jin-Xian ,
  • GUO Yue-Qiu ,
  • DONG Xiang-Ting ,
  • LI Zhi-Guo ,
  • LIU Gui-Xia
Expand
  • School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, China

Received date: 2009-08-10

  Revised date: 2009-11-17

  Online published: 2010-04-27

Fold

摘要

采用静电纺丝技术，以Ti(SO4)2、聚乙烯吡咯烷酮（PVP，Mr=1300000)、稀土氧化物和N,N-二甲基甲酰胺(DMF)为原料，成功地制备了TiO2、
Y/TiO2和Nd/TiO2纳米纤维.用XRD、FESEM、TEM和TGDTA等分析手段对样品进行了表征.XRD分析结果表明，当焙烧温度为550℃时得到纯锐钛矿
相RE/TiO2（RE=Y, Nd）纳米纤维，900℃时得到纯金红石型RE/TiO2（RE=Y, Nd）纳米纤维，稀土离子显著降低了TiO2的晶格参数.FESEM分析结
果表明，RE/TiO2（RE=Y, Nd）纳米纤维直径约为50nm、长度>300μm.以罗丹明B和苯酚为目标降解物，研究了三种催化剂的光催化性能.其中，
1.5mol%Y/TiO2光催化剂对罗丹明B的降解效率较高，而1.0mol%Nd/TiO2对苯酚具有较好的降解活性.因此，掺杂不同稀土离子的TiO2纳米纤维对
不同降解物的降解能力不同.

关键词： 静电纺丝技术; TiO2纳米纤维; 稀土; 罗丹明B; 苯酚; 光催化

本文引用格式

王进贤 , 郭月秋 , 董相廷 , 李志国 , 刘桂霞 . 钇或钕掺杂TiO2纳米纤维的制备及光催化性能研究[J]. 无机材料学报, 2010 , 25(4) : 379 -385 . DOI: 10.3724/SP.J.1077.2010.00379

Abstract

TiO2 nanofibres, Y3+-doped and Nd3+-doped TiO2 nanofibres were successfully fabricated by electrospinning using Ti(SO4)2,
polyvinyl pyrrolidone(PVP, Mr=1300000), rare earth oxides and dimethyl formamide(DMF) as raw materials. The samples were
characterized by XRD, FESEM, TEM, and TGDTA. XRD analysis indicated that RE/TiO2(RE=Y, Nd) nanofibres with pure anatase
typed phase and pure rutiletyped phase were obtained by calcination of the relevant composite fibres at 550℃ and 900℃,
respectively, and the lattice parameters of TiO2 were remarkably reduced by the doping rare earth ions. FESEM analysis
revealed that the average diameter of the RE/TiO2(RE=Y, Nd) nanofibres was about 50nm, and their length was greater than 300
μm. Photocatalytic properties of the three nanofibres were investigated by degradation of rhodamine-B and phenol. The
results showed that the degradation rate of 1.5mol%Y/TiO2 nanofibres was higher for rhodamine-B, while the degradation rate
of 1.0mol%Nd/TiO2 nanofibres was higher for phenol. Therefore, the degradation activity of rare earth ions-doped TiO2
nanofibres changed with the different doping rare earth ions and degradation compounds.

Key words： electrospinning; TiO2 nanofibres; rare earth; rhodamineB; phenol; photocatalysis

参考文献

[1］胡学斌, 徐 璇, 吉芳英, 等(HU Xue-Bin, et al). 疏水性光催化剂的制备及其催化动力学. 无机材料学报(Journal of Inorganic
Materials), 2009, 24(6): 1115-1120.
［2］李秀婷, 柳丽芬, 杨凤林, 等(LI Xiu-Ting, et al). Pt/TiO2光催化氧化还原耦合反应脱除水中无机氮. 无机化学学报(Chinese
Journal of Inorganic Chemistry), 2006, 22(7): 1180-1186.
［3］Begum Noor Shahina, Farveez Ahmed H M, Gunashekar K R. Effects of Ni doping on photocatalytic activity of TiO2 thin
films prepared by liquid phase deposition technique. Bull. Mater. Sci., 2008, 31(5): 747-751.
［4］Barakat M A, Schaeffer H, Hayes G, et al. Photocatalytic degradation of 2-chlorophenol by codoped TiO2 nano-
particles. Applied Catalysis B:Environmental, 2004, 57(1): 23-30.
［5］田宝柱, 李春忠, 顾 锋, 等(TIAN Bao-Zhu, et al). 喷雾燃烧热分解制备Cr掺杂TiO2纳米粒子的可见光催化性能. 无机材料学报
(Journal of Inorganic Materials), 2009, 24(4): 661-665.
［6］卢旭东, 姜承志, 苏会东. 低量Gd3+掺杂TiO2粉体的制备及催化活性. 环境科学与技术, 2008, 31(8): 26-31.
［7］井立强, 张 新, 屈宜春(JING Li-Qiang, et al), 等. 掺杂镧的TiO2纳米粒子的光致发光及其光催化性能. 中国稀土学报(J.Rare
Earth), 2004, 22(6): 746-750.
［8］Li F B, Li X Z, Ao C H, et al. Enhanced photocatalytic degradation of VOCs using Ln3+-TiO2 catalysts for indoor air
purification.Chemosphere, 2005, 59(6): 787-800.
［9］姜洪泉, 王 鹏, 卢丹丹, 等(JIANG Hong-Quan et al). TiO2/Gd2O3纳米粉体的制备、表征及光催化活性. 无机化学学报(Chinese
Journal of Inorganic Chemistry), 2006, 22(1): 73-78.
［10］Zeng Q G, Ding Z J, Zhang Z M. Synthesis, structure and optical properties of Eu3+/TiO2 nanocrystals at room
temperature. Journal of Luminescence, 2006, 118(2): 301-307.
［11］Wang Zhengpeng，Xu Jun，Cai Weimin, et al. Visible light induced photo-degradation of organic pollutants on nitrogen
and fluorine codoped TiO2 photocatalyst. Journal of Environmental Sciences, 2005, 17(1): 76-80.
［12］Li Yuexiang, Xie Chengfu, Peng Shaoqin, et al. Eosin Ysensitized nitrogendoped TiO2 for efficient visible light
photocatalytic hydrogen evolution. Journal of Molecular Catalysis A: Chemical, 2008, 282(1/2): 117-123.
［13］许金生, 余润兰, 冯泳兰, 等(XU Jin-Sheng, et al).Fe3+,Ce3+共掺杂纳米TiO2的相变及其降解水中CHCl3的催化性能. 中国有色金属
学报(T.Nonferr. Metal Soc.), 2006, 16(12): 2092-2097.
［14］Liu Zhongqing, Zhou Yanping, Li Zhenghua, et al. Enhanced photocatalytic activity of (La, N) codoped TiO2 by TiCl4
sol-gel autoigniting synthesis. Journal of University of Science and Technology Beijing, 2007, 14(6): 552-557.
［15］崔启征, 董相廷, 于伟利, 等(CUI Qi-Zheng, et al). 静电纺丝技术制备无机物纳米纤维的最新研究进展. 稀有金属材料与工程(Rare
Metal Mat.Eg.), 2006, 35(7): 1167-1171.
［16］张双虎, 董相廷, 徐淑芝, 等(ZHANG Shuang-Hu, et al). 静电纺丝技术制备TiO2@SiO2亚微米同轴电缆与表征. 化学学报(Acta
Chim.Sinica), 2007, 65(23): 2675-2679.
［17］Nuansing Wiwat, Ninmuang Siayasunee, Jarernboon Wirat, et al. Structural characterization and morphology of electrospun
TiO2 nanofibers. Materials Science and Engineering B, 2006, 131(1/2/3): 147-155.
［18］刘 莉, 董相廷, 王进贤, 等(LIU Li, et al). 静电纺丝法制备Y2O3纳米纤维与表征.中国稀土学报(J. Rare. Earth), 2008, 26(4):
400-404.
［19］高续波, 董相廷, 王进贤, 等. 静电纺丝法制备Y3Al5O12纳米纤维. 应用科技, 2008, 35(6): 52-56.
［20］徐淑芝, 张双虎, 董相廷, 等(XU Shu-Zhi, et al).静电纺丝技术制备TiO2空心纳米纤维与表征. 硅酸盐学报(Journal of the Chinese
Ceramic Society), 2007, 35(10): 1302-1305.
［21］李从举, 翟国钧, 付中玉， 等(LI Cong-Ju, et al).TiO2纳米纤维无纺布的制备及光催化性能研究. 无机化学学报(Chinese Journal
of Inorganic Chemistry), 2006, 22(11): 2061-2064.
［22］卢维奇, 王德清, 何肖群, 等(LU Wei-Qi, et al). 钆及双稀土元素掺杂TiO2可见光催化降解罗丹明B的研究. 中国稀土学报(J. Rare
Earth), 2007, 25(4): 427-431.
［23］樊彩梅, 唐 琦, 孙彦平(FAN Cai-Mei, et al). 掺杂钕离子纳米TiO2的制备及光催化降解水中苯酚的研究. 稀有金属(Rare Metals),
2006, 30(6): 774-778.
［24］石建稳, 郑经堂, 胡 燕, 等(SHI Jian-Wen, et al). Ho掺杂对纳米TiO2晶体结构和光催化性能的影响. 硅酸盐学报(Journal of the
Chinese Ceramic Society), 2007, 35(2): 182-186.
［25］Musiá S, Gotiá M, Ivanda M, et al. Chemical and microstructural properties of TiO2 synthesized by solgel procedure.
J. Mat. Sci. Eng., 1997, 47(1): 33-41.
［26］Kim S F, David J C, John R B, et al. IR spectroscopy of surface water and hydroxyl species on nanocrystalline TiO2
films. Langmuir, 2001, 17(3): 816-820.
［27］高 兰, 马会茹, 刘秧生, 等（GAO Lan,et al）. 硫酸改性TiO2粒子的表征与电流变性能研究.无机材料学报(Journal of Inorganic
Materials), 2009, 24(6): 11211124.
［28］Xu Anwu,Gao Yuan,Liu Hanqin.The preparation, characterization and their photocatalytic activities of rare-earth
doped TiO2 nanoparticles. J. Catal., 2002, 207(2): 151-157.
［29］Horikoshi S, Hidaka H, Serpone N. Environmental remediation by an integrated microwave/UVillumination method. 1.
Microwaveassisted degradation of rhodamineB dye in aqueous TiO2 dispersions. Environmental Science & Technology, 2002,36
(6): 1357-1366.
［30］周 彤, 吴纯德, 王晓蕾, 等. 超声协同纳米TiO2光催化降解水中苯酚机理的研究.分析科学学报, 2005, 21(3): 259-261.
［31］胡学香. 纳米二氧化钛及复合材料的光催化机理研究. 北京: 北京化工大学硕士论文, 2003.
Options
文章导航

/

〈 〉