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无机材料学报

无机材料学报 >

2009 , Vol. 24 >Issue 5: 943 - 947

DOI: https://doi.org/10.3724/SP.J.1077.2009.00943

研究论文

烧蚀产物ZrO2对ZrC改性C/C复合材料烧蚀的影响

  • 沈学涛 ,
  • 李克智 ,
  • 李贺军 ,
  • 兰逢涛 ,
  • 冯 涛
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  • （西北工业大学 陕西省炭/炭复合材料工程技术研究中心, 超高温复合材料国防科技重点实验室, 西安 710072）

收稿日期: 2008-12-18

  修回日期: 2009-03-16

  网络出版日期: 2009-09-20

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Effect of ZrO2 from the Oxidation of ZrC on Ablation of ZrC Modified Carbon/Carbon Composites

  • SHEN Xue-Tao ,
  • LI Ke-Zhi ,
  • LI He-Jun ,
  • LAN Feng-Tao ,
  • FENG Tao
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  • (C/C Composites Technology Research Center, National Key Laboratory of Thermostructure Composite Materials, Northwestern Polytechnical University, Xi’an 710072, China)

Received date: 2008-12-18

  Revised date: 2009-03-16

  Online published: 2009-09-20

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摘要

采用ZrOCl2溶液浸渍法把含锆组元引入碳纤维预制体, 结合热梯度化学气相渗透、高温石墨化工艺制备了ZrC改性C/C复合材料. 用氧乙炔烧蚀测试材料的烧蚀性能, XRD测试材料烧蚀前后的物相组成, 采用SEM观察材料的微观形貌. 烧蚀结果表明：随着烧蚀次数的增加, 若每次烧蚀后不去除ZrO2, 材料的线、质量烧蚀率呈先增加后减小的趋势, 最后趋于稳定; 若每次烧蚀后去除ZrO2, 材料的线、质量烧蚀率均呈增大的趋势. 产物ZrO2的蒸发吸收了材料烧蚀表面的热量, 减缓了火焰对烧蚀表面的冲蚀, 材料的线烧蚀率减小, 然而, ZrO2的蒸发会增加材料的质量损失速度, 导致材料的质量烧蚀率增大.

关键词： ZrC; C/C复合材料; 烧蚀; 氧乙炔

本文引用格式

沈学涛 , 李克智 , 李贺军 , 兰逢涛 , 冯 涛 . 烧蚀产物ZrO2对ZrC改性C/C复合材料烧蚀的影响[J]. 无机材料学报, 2009 , 24(5) : 943 -947 . DOI: 10.3724/SP.J.1077.2009.00943

Abstract

Zirconium-containing carbon fiber preform was prepared by ZrOCl2 aqueous solution impregnation. ZrC modified carbon/carbon (C/C) composites were obtained by a series of procedures combined with densification by thermal gradient chemical vapor infiltration (TCVI) and high-temperature graphitization. The ablation properties were tested in an oxyacetylene torch. The phase composition and morphology of the composites were investigated by XRD and SEM, respectively. Results show that, with increasing ablation times, the linear and mass ablation rates increase firstly and then decrease, remain constant finally when ZrO2 is not removed after each ablation. Meanwhile, the linear and mass ablation rates increase with the ablation time in case of removing ZrO2 after each ablation. The evaporation of ZrO2 will absorb heat and relieve erosion from oxyacetylene flame on the ablated surface of the specimen, and also accelerate the mass loss of the specimen, which leads to the decrease of the linear ablation rate and increase of mass ablation rate of the composites.

Key words： ZrC; C/C composites; ablation; oxyacetylene

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