镍基底上生长CNx纳米管薄膜的研究

无机材料学报

镍基底上生长CN_x纳米管薄膜的研究

丁佩^1,2; 郭新勇³; 张经纬³; 晁明举²; 梁二军²

1. 郑州航空工业管理学院应用科学系, 郑州 450015; 2. 郑州大学物理工程学院材料物理国家教育部重点实验室, 郑州 450052; 3. 河南大学特种功能材料实验室, 开封 475001

收稿日期:2004-03-02 修回日期:2004-06-03 出版日期:2005-03-20 网络出版日期:2005-03-20

Growth of CN_x Nanotubes Films on Ni Substrates

DING Pel^1,2; GUO Xin-Yong³; ZHANG Jing-Wei³; CHAO Ming-Ju²; LIANG Er-Jun²

1. Department of Applied Science; Zhengzhou Institute of Aeronautical Industry Management; Zhengzhou 450015; China; 2.School of Physical Science and Engineering; Key Laboratory of Materials Physics; Ministry of Education of China; Zhengzhou University; Zhenzhou 450052; 3.Laboratory of Special Functional Materials; Henan University; Kaifeng 475001; China

Received:2004-03-02 Revised:2004-06-03 Published:2005-03-20 Online:2005-03-20

摘要/Abstract

摘要： 以乙二胺为前驱液,采用高温热解法,860℃下在镍基底表面生长CN_x纳米管薄膜.研究了经过不同实验条件处理过的镍基底表面的CN_x纳米管的生长情况.实验结果表明, 经过不同的预处理过程后,镍基底对CN_x纳米管的生长表现出不同的催化性能,经过氢氟酸 (HF)浸泡10min并无水乙醇超声清洗过的镍基底有利于具有"竹节状"结构的CN_x纳米管的生长.

关键词: 镍基底, CN_x纳米管, 高温热解, 拉曼光谱

Abstract: The CN_x nanotubes films were fabricated by pyrolyzing ethylenediamine on Ni substrates at 860℃. The growth of CN_x nanotubes on Ni substrates pretreated in different conditions was investigated. It is found that the Ni substrates pretreated in different conditions have different catalytic effects on the growth of CN_x nanotubes, and the CN_x nanotubes with "bamboo-like" structure grow preferentially on the Ni substrate dipped in HF for 10 min and followed by ultrasonically cleaned in ethanol.

Key words: Ni substrates, CN_x nanotubes, thermal decomposition, Raman spectra

中图分类号:

TB383
O643

丁佩,郭新勇,张经纬,晁明举,梁二军. 镍基底上生长CN_x纳米管薄膜的研究[J]. 无机材料学报.

DING Pel,GUO Xin-Yong,ZHANG Jing-Wei,CHAO Ming-Ju,LIANG Er-Jun. Growth of CN_x Nanotubes Films on Ni Substrates[J]. Journal of Inorganic Materials.

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