无机材料学报

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La0.5Ca0.5MnO3中Ca位上Ba掺杂效应研究

姜勇1,2; 李广2; 曾祥勇1; 汤萍2; 孙霞2; 黄真2; 袁松柳1   

  1. 1. 华中理工大学物理系; 武汉 430074; 2. 中国科学院等离子体物理研究所; 合肥 230031
  • 收稿日期:1999-06-14 修回日期:1999-07-12 出版日期:2000-06-20 网络出版日期:2000-06-20

Ba-Doping Effect on Ca Sites of La0.5Ca0.5MnO3

JIANG Yong1,2; LI Guang2; ZENG Xiang-Yong1; TANG Ping2; SUN Xia2; HUANG Zhen2; YUAN Song-Liu 1   

  1. 1.Department of Physics; Huazhong University of Science and Technology Wuhan 430074; China; 2.Institute of Plasma Physics; Chinese Academy of Sciences; Hefei 230031; China
  • Received:1999-06-14 Revised:1999-07-12 Published:2000-06-20 Online:2000-06-20

摘要: 用固态反应法制备了具有单相结构的La0.5Ca0.5-xBaxMnO3系列样品,其结构随Ba含量增加由立方晶系转变为典型的正交晶系.零场下输运性质实验表明,在较低掺杂量时,系统在整个温区显示半导体型导电特征,而当掺杂量超过0.14时,系统发生由半导体到金属的转变,且转变的温度随掺杂量增加而移向高温瑞.基于对实验结果的分析,就Ca位上Ba掺杂所起的作用进行了初步探讨.

关键词: 超大磁电阻效应, 双交换作用, 电荷有序化, A位平均离子半径

Abstract: Single-phase polycrystalline samples of La0.5Ca0.5-xBaxMnO3 (0.1≤ x≤0.5) were fabricated
by the solid state reaction method. With increasing the content of Ba doping, the structural transition occurs from cubic to orthorhombic.
The measurement of resistance as a function of temperature under zero field shows that the samples of lower doping behave a semiconducting
behavior in the whole studied temperature range, and a transition from semiconducting to metallic states appears in the samples x≥0.14. The
transition moves toward the high temperature region with increasing the doping content. The role of Ba doping on the Ca sites was discussed on
the basis of analyzing the experimental data.

Key words: CMR, double-exchange interaction, charge-ordering, average A-site ions radius

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