水解法锑白的晶型结构控制机理

无机材料学报

水解法锑白的晶型结构控制机理

肖松文¹; 肖骁²; 刘志宏²; 李启厚²; 张多默²

1. 长沙矿冶研究院, 长沙 410012; 2. 中南工业大学, 长沙 410083

收稿日期:1999-08-20 修回日期:1999-10-21 出版日期:2000-08-20 网络出版日期:2000-08-20

Polymorph Control Mechanism of Antimony White Powders by Hydrolysis

XIAO Song-Wen¹; XIAO Xiao²; LIU Zhi-Hong²; LI Qi-Hou²; ZHANG Duo-Mo ²

1.Changsha Research Institute of Mining & Metallurgy; Changsha 410012; China; 2.Central South University of Technology; Changsha 410083, China

Received:1999-08-20 Revised:1999-10-21 Published:2000-08-20 Online:2000-08-20

摘要/Abstract

摘要： 本文基于负离子配位多面体生长基元模型，分析确定了两种晶型锑白的不同结构基元：ＳｂＯ_３配位四面体与ＳｂＯ_３＋３Ｅ星状四面体；详细探讨了水解法制锑白时水解介质等条件对其晶型结构影响的机理，得到了水解法制锑白时控制晶型结构的规律．

关键词: 负离子配位多面体, 锑白, 生长基元, 晶型结构

Abstract: The different growth unites of two polymorph antimony white were analyzed and determined according to the theoretical model of growth units with coordination polyhedron structure of anion, and the chajnge characteristic of the polymorph structure of antimony white prepared by hydrolysis was discussed in detail, and the polymorph control mechanism of antimony white powders prepared by hydrolysis was revealed.

Key words: coordination polyhedron structure of anion, antimony white, structure growth unit, polymorph

中图分类号:

TF123

肖松文,肖骁,刘志宏,李启厚,张多默. 水解法锑白的晶型结构控制机理[J]. 无机材料学报.

XIAO Song-Wen,XIAO Xiao,LIU Zhi-Hong,LI Qi-Hou,ZHANG Duo-Mo. Polymorph Control Mechanism of Antimony White Powders by Hydrolysis[J]. Journal of Inorganic Materials.

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