新型太阳能材料C60Pt(dppp)配合物的合成及性能

doi:10.3724/SP.J.1077.2009.00018

无机材料学报

新型太阳能材料C₆₀Pt(dppp)配合物的合成及性能

杨绳岩, 张娜，吴振奕

厦门大学化学化工学院化学系，厦门 361005

收稿日期:2008-03-11 修回日期:2008-05-19 出版日期:2009-01-20 网络出版日期:2009-01-20

Synthesis and Property of Noval Solar Energy of C₆₀Pt(dppp)

YANG Sheng-Yan, ZHANG Na, WU Zhen-Yi

Department of Chemistry, Xiamen University, College of Chemistry and Chemical Engineering, Xiamen 361005, China

Received:2008-03-11 Revised:2008-05-19 Published:2009-01-20 Online:2009-01-20

摘要/Abstract

摘要： 以C₆₀及双齿膦dppp为配体,在氮气氛下合成出C₆₀Pt(dppp)配合物，采用质谱、元素分析、红外光谱、紫外可见光谱以及光电子能谱等手段对产物进行表征.同时研究了产物的光电性能及氧化还原性能.光伏效应研究结果表明：产物具有优良的光电转化性能，尤其是在BQ/H₂Q介质电对中，光生电压最大达到371mV；当C₆₀Pt(dppp)薄膜厚度为1μm时，光伏效应值最大.

关键词: 富勒烯, 铂配合物, 光电性能

Abstract: The fullerene complex C₆₀Pt(dppp) was prepared by reacting C₆₀ with dppp in nitrogen atmosphere. The synthesized fullerene complex was characterized by means of Mass Spectrometry (MS), Elemental Analysis, FT-IR, UV-Vis and XPS. Besides these, the photoelectric properties and redox property of this complex were also studied. The results show that the greatest value of photovotaic potential is 371mV in the benzoquinone/hydroquinone redox couple, and the value of photovoltaic effects reach the maximum when the thickness of complex film is 1μm. Based on the merits mensioned above, the complex has excellent photoelectric properties, therefore it has potential application in solar cells.

Key words: fullerene, platinum complex, photoelectric properties

中图分类号:

O641
O644

杨绳岩,张娜,吴振奕. 新型太阳能材料C₆₀Pt(dppp)配合物的合成及性能[J]. 无机材料学报, DOI: 10.3724/SP.J.1077.2009.00018.

YANG Sheng-Yan,ZHANG Na,WU Zhen-Yi. Synthesis and Property of Noval Solar Energy of C₆₀Pt(dppp)[J]. Journal of Inorganic Materials, DOI: 10.3724/SP.J.1077.2009.00018.

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新型太阳能材料C₆₀Pt(dppp)配合物的合成及性能

Synthesis and Property of Noval Solar Energy of C₆₀Pt(dppp)

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