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无机材料学报

无机材料学报

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碳化法制备片状碳酸钙的研究

文艳; 向兰; 金涌   

  1. 清华大学化工系 北京 100084
  • 收稿日期:2001-10-29 修回日期:2001-12-06 出版日期:2002-11-20 网络出版日期:2002-11-20

Preparation of Plate-like Calcium Carbonate

WEN Yan; XIANG Lan; JIN Yong   

  1. Department of Chemical Engineering; Tsinghua University; Beijing 100084; China
  • Received:2001-10-29 Revised:2001-12-06 Published:2002-11-20 Online:2002-11-20

PDF (PC)

994

被引次数

33

摘要： 初步探讨了快速碳化低固含氢氧化钙悬浮液制备片状碳酸钙的可行性,考察了初始固含率、分布器孔径、二氧化碳气量、温度等过程参数对产物形貌的影响,对碳化规律进行了初步分析,结果表明降低溶液pH值、强化CO2吸收、维持较低的Ca2+/CT比值均利于片状产物的形成.最佳工艺条件为:悬浮液初始固含率<0.1％(m),分布器孔径0.7～15mm;CO2气量100～400mL/min,温度20～30℃.

关键词: 片状碳酸钙, 碳化法, 形貌控制

Abstract: A fast carbonation process was developed to synthesis plate-like calcium carbonate in dilute lime slurry.
The influence of some process factors, such as the solid concentration of lime slurry, the orifice diameter of gas distributor, the flow rate of
CO2, and the reaction temperature on the morphology of CaCO3 was investigated. The experimental results and the thermodynamic calculation
indicate that lower pH, stronger absorbing of CO2, and lower Ca2+/CT values are favorable for the formation of plate-like CaCO3.
The suitable carbonation conditions are as follows: <0.1%(m) of the solid concentration of lime slurry, 0.7～1.5mm of the orifice diameter of the gas
distributor, 100～400mL/min of CO2 flow rate, and temperature 20～30℃.

Key words: plate-like calcium carbonate, carbonation, morphology control

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