钙钛矿太阳能电池无机空穴传输材料的研究进展

陈雨, 林埔安, 蔡冰, 张文华

Research Progress of Inorganic Hole Transport Materials in Perovskite Solar Cells

CHEN Yu, LIN Puan, CAI Bing, ZHANG Wenhua

表1 无机空穴传输材料的基本性质(Spiro-OMeTAD作为对比)

Table 1 Properties of inorganic hole transport materials (Spiro-OMeTAD for comparison)

Material Hole concentration, N/cm-3 Hole mobility, μ/(cm2·V-1·s-1) Conductivity, σ/(S·cm-1) Sprio-OMeTAD with Li-TFSI, etc. 7.13×1015[19] 0.779[19] 1.53×10-3[13] NiO 5.3×1018[20] 0.12[20] 1.66×10-4[21] Cu:NiO 7.3×1019[22] ~0.2[22] 1.25×10-3[23] Ni0.8Li0.05Mg0.15O 6.46×1018[24] - 2.23×10-3[24] CuGaO2 3.098×1019[25] - 4.625×10-3[25] Zn:CuGaO2 1.328×1020[25] - 1.39×10-2[25] CuCrO2 - 0.1-1.0[26] 2.9×10-2[27] In:CuCrO2 7.1×1018[27] 0.75[27] 6.9×10-2[27] CuScO2 - - 2.11×10-3[28] CuSCN - 1.2×10-3[21] - Co3O4 - 1.49×10-2[29] - Co3O4-SrCO3 - 6.33×10-2[29] -