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三元层状材料结构调控及性能研究进展
丁浩明1,2,3(), 李勉1,3, 李友兵1,3, 陈科1,3, 肖昱琨1,3, 周洁4, 陶泉争4, 尹航5, 柏跃磊5, 张毕堃6, 孙志梅6, 王俊杰7, 张一鸣1,3, 黄振莺8, 张培根9, 孙正明9, 韩美康10, 赵双11, 王晨旭11, 黄庆1,3()
Progress in Structural Tailoring and Properties of Ternary Layered Ceramics
DING Haoming1,2,3(), LI Mian1,3, LI Youbing1,3, CHEN Ke1,3, XIAO Yukun1,3, ZHOU Jie4, TAO Quanzheng4, Johanna Rosen4, YIN Hang5, BAI Yuelei5, ZHANG Bikun6, SUN Zhimei6, WANG Junjie7, ZHANG Yiming1,3, HUANG Zhenying8, ZHANG Peigen9, SUN Zhengming9, HAN Meikang10, ZHAO Shuang11, WANG Chenxu11, HUANG Qing1,3()

图22. 辐照环境下MAX相材料中的缺陷产生和微观结构转变

Fig. 22. Defect generation and microstructural transformation in MAX phase materials under irradiation
(a) STEM HAADF (high-angle annular dark-field) image along [11¯20] of Ti3AlC2 irradiated with 1 MeV Au ions, showing direct evidence of cation antisite defects. The white arrows indicate the initial Al layers, whose image contrast is altered when compared with the initial hexagonal structure[295]; (b, c) Contrast profiles along line 1 and line 2 in (a), respectively, which directly show the variation of contrast arising from the formation of TiAl-AlTi antisite defects produced by ion irradiation[295]; (d) TEM image of Ti3(Si,Al)C2 being irradiated at 0.2 dpa indicating a cluster of point defects (black dots)[296]; (e-g) Phase transformation (hcp to γ to fcc solid solution) processes with chemical disorder induced by ion irradiation in a typical MAX phase, Ti3AlC2 (hcp: hexagonal close packing; fcc: face-centered cubic)[295]