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三元层状材料结构调控及性能研究进展
丁浩明1,2,3(), 李勉1,3, 李友兵1,3, 陈科1,3, 肖昱琨1,3, 周洁4, 陶泉争4, 尹航5, 柏跃磊5, 张毕堃6, 孙志梅6, 王俊杰7, 张一鸣1,3, 黄振莺8, 张培根9, 孙正明9, 韩美康10, 赵双11, 王晨旭11, 黄庆1,3()
Progress in Structural Tailoring and Properties of Ternary Layered Ceramics
DING Haoming1,2,3(), LI Mian1,3, LI Youbing1,3, CHEN Ke1,3, XIAO Yukun1,3, ZHOU Jie4, TAO Quanzheng4, Johanna Rosen4, YIN Hang5, BAI Yuelei5, ZHANG Bikun6, SUN Zhimei6, WANG Junjie7, ZHANG Yiming1,3, HUANG Zhenying8, ZHANG Peigen9, SUN Zhengming9, HAN Meikang10, ZHAO Shuang11, WANG Chenxu11, HUANG Qing1,3()

图1. 三元层状材料的发现时间轴(非完全统计)

Fig. 1. Non-exhaustive chronicle of ternary layered materials
In 1960, Ti2SC was synthesized[40]; From 1960 to 1966, a large number of ternary layered carbides/nitrides (H-phases) with an M2AX formula (211 type) were synthesized[41-42]; From 1967 to 1968, Ti3SiC2 (312 type) and a set of 312 and 211 types H-phases were produced[41,43-44]; In 1969, a typical ternary layered boride Fe2AlB2 was synthesized[7]; In 1994, Ti3AlC2 was discovered[45]; In 1996, the high purity Ti3SiC2 was produced and exhibited excellent properties, thus triggering the research upsurge to these materials[46]; In 2000, Barsoum[1] renamed H-phases as Mn+1AXn phases, short for MAX phases; In 2011, the first MXene Ti3C2Tx was discovered[28]; In 2013, the discovery of magnetocaloric effect of Fe2AlB2 raised research upsurge on ternary layered borides[9]. Also, Lu2SnC was synthesized and found to be superconducting[47]; In 2014, an o-MAX (Cr2/3Ti1/3)3AlC2 was synthesized[48]; In 2015, ternary layered borides were named as MAB phases. In addition, the first Zr-based MAX phase was discovered[10,49]; In 2017, an i-MAX (Mo2/3Sc1/3)2AlC and two noble-metal MAX phases Ti3AuC2 and Ti3IrC2 were synthesized[22,50]; In 2019, a series of MAX phases containing Cu and Zn, and a hexagonal MAB phase Ti2InB2, as well as Nb2SBxC1-x (x=0-1) were synthesized[24⇓-26,51,52]; In 2020, two i-MAB phases (Mo2/3Sc1/3)2AlB2 and (Mo2/3Y1/3)2AlB2, as well as a variety of MAX phases containing Fe, Co, Ni, and Mn were synthesized[16,19]; In 2021, MAX phases having Se atoms at the A-site were produced[53]; In 2022, o-MAX phase Ti4MoSiB2, the first MBene, and Zr2Se(B1-xSex) were synthesized[20,54-55]; In 2023, a chemical scissor-mediated structural editing strategy was proposed, which extremely expands the diversity of MAX phases and MXene[56]