基于氧化钨和氧化镍的电致变色器件研究进展

钟晓岚, 刘雪晴, 刁训刚

Electrochromic Devices Based on Tungsten Oxide and Nickel Oxide: a Review

ZHONG Xiaolan, LIU Xueqing, DIAO Xungang

表1 2016~2020年基于WO₃和NiO薄膜的电致变色器件结构与性能对比

Table 1 Comparison of structure and performance of ECDs based on WO₃ and NiO films researched from 2016 to 2020

Year	Device structure	t_c/s	t_b/s	CE/(cm²·C^-1)	ΔT/%	Cycles	Ref.
2016	ITO/NiO_x/ZrO₂:H/WO₃/ITO	116	108	-	65.2	2000	[72]
2016	ITO/NiO_x/Ta₂O₅:H/WO₃/ITO	-	-	-	60	-	[76]
2016	ITO/WO₃/LiClO₄-PC-PMMA/NiO_x/ITO	4.5	1.7	-	51.7	50000	[77]
2016	Glass/ITO/WO₃/LiNbO₃/NiO_x/ITO	45	25	-	65	-	[78]
2016	ITO/NiO_x:Ti/PVB(Li⁺)/WO₃/ITO	4.4	3.2	96	60	-	[79]
2017	Glass/ITO/WO₃/PVB-GPEF/Ni_1-_xO/ITO/Glass	9.5	16	175.34	65.8	3000	[80]
2017	Glass /ITO/NiO_x/electrolyte/WO₃/ITO	7	2	-	70	300	[81]
2017	Glass /ITO/NiO/Si₃N₄/LiNbO₃/Si₃N₄/WO₃/ITO	-	-	-	43	-	[82]
2017	ITO/NiO/Ta₂O₅/LiNbO₃/WO₃/ITO	-	-	-	34	-	[83]
2018	Glass/ITO/NiO/Si₃N₄/Li_xMg_yN/WO₃/ITO	-	-	77	40	1000	[84]
2018	Glass/ITO/WO₃/Li_2.5TaO_x/NiO/ITO	30	30	63	40	300	[71]
2018	FTO/WO₃/gel polymer electrolyte/NiO/FTO	1.2	2.6	-	43.81	20000	[85]
2018	Glass/ITO/WO₃:H/Ta₂O₅/NiO_x/ITO	-	-	24.3	42	300	[86]
2018	Glass/ITO/WO₃/LiPON/NiO/ITO	-	-	-	40	-	[74]
2018	Glass/ITO/Li_xNiO_y/LiTaO₃/WO₃/ITO	13	3.5	42	40	7000	[87]
2018	ITO/NiO_x/Ta₂O₅/LiNbO₃/Ta₂O₅/WO₃/ITO	-	-	98	52.5	10000	[88]
2018	ITO/NiO/ZrO₂/LiNbO₃/WO₃/ITO	-	-	24.3	53	-	[89]
2018	ITO/NiO/Ta₂O₅/LiNbO₃/WO₃/ITO/Glass	10	7	-	71.7	-	[90]
2019	Glass/IAI/NiO_x/LiClO₄-PC-PMMA/WO₃/IAI/Glass	2.25	2.02	31.7	55	-	[62]
2019	ITO/NiO_x/Li_xAlO_z/WO₃/ITO	5.7	2.2	76.45	74.4	10000	[75]
2019	ITO/WO₃-Nb₂O₅/Nb₂O₅/NiVO_x/ITO	7	0.7	-	33	30000	[91]
2019	ITO/WO₃/LiClO₄-PC-PMMA/NiO/ITO	3.2	1.1	130.8	45	1000	[92]
2019	ITO/NiO_x/Ta₂O₅/LiNbO₃/Ta₂O₅/WO₃/ITO	18.4	9.5	-	55.2	2500	[93]
2019	ITO/NiO_x/Ta₂O₅/WO₃/ITO	13	2	-	70.9	-	[94]
2020	Glass /ITO/WO₃/LiF/NiO/ITO	9.6	4	88.5	58.9	450	[73]
2020	ITO/WO₃/Gelatin/NiO/ITO	10	50	60.38	43.35	-	[70]
2020	ITO/Li-NiO/Li-WO₃/ITO	8.6	1.7	87.5	32	1000	[95]
2020	ITO/WO₃/LiClO₄-PC-PMMA-ACN/NiO/ITO	1.2	1.5	243	51.27	20000	[96]
2020	ITO/WO₃/LiNbO₃/Al-LiNiO_x/ITO	17.9	4.1	-	44	5000	[97]