可见光催化剂钒酸铋的可控合成及性能研究
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李杰, 宋晨飞, 逄显娟
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Controllable Synthesis and Photocatalytic Performance of BiVO4 under Visible-light Irradiation
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Jie LI, Chen-Fei SONG, Xian-Juan PANG
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表1 BiVO4(s-m)的拉曼峰位置及V-O键长和半峰宽 |
Table 1 Raman absorption band position and V-O bond length, FWHM in BiVO4(s-m) |
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pH | νs(V-O)/cm-1 | R1/nm | S1(V-O) | νas(V-O)/cm-1 | R2/nm | S2(V-O) | Valence state of V | FWHM | 1 | 828.57 | 0.17071 | 1.3264 | 708.40 | 0.17760 | 1.0431 | 5.0223 | 43.80 | 2 | 830.12 | 0.16934 | 1.3303 | 708.93 | 0.17757 | 1.0443 | 5.0352 | 44.71 | 7 | 830.83 | 0.16929 | 1.3320 | 710.53 | 0.17745 | 1.0478 | 5.0438 | 45.49 | 9 | 831.19 | 0.16927 | 1.3329 | 710.71 | 0.17744 | 1.0482 | 5.0469 | 45.93 | 11 | 829.76 | 0.16936 | 1.3294 | 709.64 | 0.17751 | 1.0459 | 5.0342 | 45.41 | 13 | 829.42 | 0.16938 | 1.3285 | 708.93 | 0.17757 | 1.0443 | 5.0298 | 44.04 |
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